Nga nghiên cứu thành công siêu vật liệu tàng hình

Một nhóm các nhà nghiên cứu tại Đại học Khoa học và Công nghệ Quốc gia (NUST MISIS) ở Moscow, Nga vừa sáng tạo thành công siêu vật liệu độc đáo có thể giúp các phương tiện quân sự tàng hình, tạp chí khoa học danh tiếng Physical Review cho hay.

Theo Physical Review, siêu vật liệu này không thể tìm thấy trong tự nhiên. Nó có khả năng tác động lên sóng điện từ như ngăn chặn, hấp thụ, tăng cường hoặc bẻ cong khiến nó trở nên vô hình với các loại sóng. Siêu vật liệu này có thể sử dụng rộng rãi trong việc phát triển vũ khí hoặc siêu máy tính mới.

Giám đốc dự án Alexei Basharin cầm trên tay loại vật liệu có khả năng chế tạo phương tiện quân sự tàng hình.
Giám đốc dự án Alexei Basharin cầm trên tay loại vật liệu có khả năng chế tạo phương tiện quân sự tàng hình.

Dự án về vật liệu tàng hình này được một nhóm các nhà khoa học của NUST MISIS phối hợp với trường Đại học Crete, Hy Lạp thực hiện. Năm 2016, Nga và Hy lạp ký một biên bản ghi nhớ về hợp tác nghiên cứu công nghệ lượng tử và chương trình tài chính chung cho nghiên cứu này.

Giám đốc dự án, ông Alexei Basharin cho biết: “Phần thực nghiệm của nghiên cứu là tạo ra siêu vật liệu cấu thành từ một mạng lưới bằng phẳng của cái gọi là siêu phân tử cắt từ khối thép thông thường“.

Ông Basharin nói thêm, nhờ có cấu trúc và hình dạng phân tử khác biệt nên các nhà khoa học đã tạo nên vật liệu có tính chất hoàn toàn độc đáo. Ngoài khả năng tàng hình, siêu vật liệu còn có thể ứng dụng chế tạo thiết bị cảm biến siêu nhạy có thể phát hiện vũ khí hóa học và chất nổ.

Cơ quan báo chí của NUST MISIS cho biết trong một tuyên bố: “Với sự bổ sung của chất bán dẫn phi tuyến, siêu vật liệu có thể điều chỉnh phù hợp với công nghệ tàng hình, giúp các phương tiện quân sự tàng hình với sóng hồng ngoại, sóng vô tuyến và các loại sóng khác. Cơ quan Thông tin Vệ tinh Nga (RSCC) và các tổ chức không gian khác đã thể hiện sự quan tâm đến vật liệu mới này”.

The Hellmann of the Hellmann-Feynman theorem

The Hellmann-Feynman theorem is well known in quantum mechanics, perhaps even more so in quantum chemistry. Feynman is of course Richard Feynman, who gave a proof of the theorem in his undergraduate thesis. But who is Hellmann?

Hans Hellmann was born in Germany in 1903. He received his PhD in 1929 from University of Stuttgart. He proved the famous theorem in 1933. Shortly after, in 1934 Hellmann escaped from Nazi Germany to the Soviet Union. It was in the USSR where he wrote the first textbook in quantum chemistry, predating Linus Pauling’s book by a few years. He tragically died in 1938 during Stalin’s Great Terror. Below is an excerpt from a biography written by his son Hans Hellmann Jr., which appeared in the new edition of Hellmann’s quantum chemistry textbook Einführung in die Quantenchemie (Springer Spektrum, 2015). Caution: this translation relies heavily on Google Translate. All inaccuracies in translation belong to me.

Portrait of Hans Hellmann by Tatjana Livshits (1999)

… On November 1, 1931, at the age of 28, my father got a job as a lecturer in physics (Physik-Dozent) at the University of Veterinary Medicine Hanover, despite the fact that his Habilitation has not been completed yet. His mentor, Professor Fues, assured that it was imminent. In March and July of 1933, two important papers written by my father appeared in the journal Zeitschrift für Physik. In the first paper, he presented a method by which one can make quantitative statements about the energy of polyatomic molecules on the basis of spectroscopic data of their diatomic fragments. The other work highlights the role of the kinetic energy of the electrons in the covalent bond and contained the virial theorem and the theorem known today as the Hellmann-Feynman theorem. Both works would form the basis of my father’s Habilitation thesis.

But my father was denied the Habilitation. Following the appointment of Adolf Hitler as Chancelor on January 30, 1933, several new laws directed against political opponents, and especially against Jews, were passed. The first set of laws, including the “Law for the Restoration of the Professional Civil Service” of April 7, 1933, took aim at Jewish officials. They could not fulfill their new obligation – to prove their “Aryan origins” – and lost their job. A little later, with the Reich Civil Service Act of June 30, 1933, those in the so-called “mixed marriages” were also affected.

My parents faced hard times. With the Habilitation application, my father must declare the “racial origins” of his wife [who was from a Jewish family in Ukraine], but he refused to submit the requested information. My father was never a member of any political party, but he had political beliefs and never concealed his negative attitude towards National Socialism. In contrast, most students at the University of Veterinary Medicine welcomed the “new order” with enthusiasm. They would greet my father at his lectures with disruptive and hostile noise.

My parents had in their library some books that were banned at the time: Heine, Zweig, Fallada, and magazines with articles by progressive authors. Since keeping them was dangerous, they had to destroy them. My mother told me that once, I reported enthusiastically at my kindergarten: “Yesterday my parents burned a lot of red books!” (they were issues of the [leftist] magazine “Die Weltbühne”). The teacher became scared and brought me home. That was the first, but unfortunately not the last, political lesson in my life.

In the autumn of 1933, the Prussian Culture Ministry prohibited the University of Veterinary Medicine from conferring Habilitation on my father. On December 24, 1933, he was informed that his lecturer position was to be terminated effective March 31, 1934, as his Habilitation was no longer expected due to the “non-Aryan origins” of his wife. His doctoral adviser Erich Regener would be dismissed “only” in 1938.

The continuation of scientific collaboration with colleagues at the Technical University of Hanover became impossible. There, my father had had very intensive discussions with Wilhelm Jost, Privatdozent of Physical Chemistry, on the “problem of the nature of the chemical forces.” They still managed to publish, as two papers in the journal Zeitschrift für Elektrochemie (1934/1935), the clear understanding based on quantum mechanics that they worked out, but the second paper had Wilhelm Jost listed as the sole author. Later, these two papers would form the basis of the first chapter of my father’s two textbooks of quantum chemistry.

Like many scientists, particularly those from Göttingen, a center of the development of quantum mechanics, my father had to emigrate with his family. But to where? A fateful decision was made in favor of the Soviet Union. Why? There were probably two deciding factors. First, my father had a certain sympathy for socialist ideas. Second, my mother came from there (she did not lose her citizenship) and still had relatives there. Later I learned from her that my father also had other invitations, including some from America. From about 1930, he had been looking for a job in the Soviet Union. Perhaps he talked about it with his sister back then.

Hans Hellmann and his sister Greta (c. 1930)

Through the mediation of Victor Weisskopf, still in Göttingen at the time, he got two invitations. The first was from the Ukrainian Physico-Technical Institute in Kharkov (now Kharkiv), where several well-known physicists (among others Alexander Weissberg and Lev Shubnikov, a few years later also Lev Landau) were working at that time. The second invitation was from the Physics Institute of the University of Dnepropetrovsk, where Boris Finkelstein was very interested in problems of quantum chemistry. But in both occasions the Soviet authorities refused to issue the necessary entry documents. Then came 1932 when, again with the help of colleagues in Göttingen, he made contact with the Karpov Institute in Moscow, then a leading center of physico-chemical research in the Soviet Union. After a meeting in Berlin with academician Alexander Frumkin, Deputy Director of the Karpov Institute, my father received an official invitation to Moscow and an attractive job offer. In March 1934 we got the necessary entry and exit documents. We bid farewell to our dear relatives and left Germany. Traveling by train from Berlin, we arrived in Moscow on April 31, 1934. My mother’s aunt Maria Minchina picked us up at Belorussian-Baltic Station. Her first words were: “How did you decide to come here? You are crazy!” [“Сумасшедшие, куда вы приехали?”, according to a Russian source].

*     *

The Karpov Institute in Moscow was at that time very well financed by the government. The research carried out there were important both for the economy and the military. The directors of the Institute were two academicians, Alexei Bach, a biochemist, and Alexander Frumkin, a physicist. In the “Department of the Structure of Matter” under the leadership of Yakov Syrkin, my father was hired as the “Head of the Theory Group.” He was well received at the Institute and, which was particularly important for him, could now fully devote his knowledge and work to science. At that time, foreign scientists in the Soviet Union had some privileges. Of course, complete loyalty was demanded in return. My father had the freedom to plan his working hours, and he was also able to work at home a lot. In his letters to his mother, who was then living in Hamburg, he described the atmosphere at the Institute and the local working conditions in enthusiastically positive terms. Not a single word about the small two-room apartment or the lack of certain foods. He talked about his work and his contacts with foreign colleagues, for example, at an international conference in Kharkov in 1934.

This photo from the AIP archive was mislabeled. The person to the left of Niels Bohr, under the red arrow, is Hans Hellmann, and to the left of him, Yuri Rumer.

After numerous insults and humiliations in Hanover during the first year of the Nazi regime, he was very happy with his new life in Moscow, and the whole family was also mostly happy. In the summer of 1935 my grandmother came to the Soviet Union to visit us in the for the first and only time. She spent a short vacation in the Crimea with her son during this visit.

Early in 1935, the doctorate, the Russian equivalent of Habilitation, was conferred on my father. Approximately every two months he would publish a scientific paper. At a meeting in Dnepropetrovsk he was elected to the organizing committee of a quantum chemistry conference held in 1936. He was honored several times with monetary awards for his research and results. In June 1936 my father became a Soviet citizen, in November his starting salary of 700 rubles was increased to 1200 rubles, and in December he was invited to give a lecture at the Academy of Sciences. Shortly afterwards, on January 1, 1937, he was appointed a “Full Member of the Karpov Institute” (which corresponds to the title of a professor at a university), and in autumn 1937 became a “Senior Scientist.” In this period of about three and a half years in Moscow, my father had advised and mentored a number of young PhD students and postdocs: V. Kasatochkin, K. Maevsky, M. Mamotenko, S. Pshezhetsky, N. Sokolov, and M. Kovner.

At least since 1933 my father had been planning to write a monograph on his field of quantum chemistry. The above-mentioned join work with Wilhelm Jost in Hanover would form part of this monograph. The first version of the manuscript was finished before emigration, but remained with Jost, who tried in vain to find a publisher in Germany. Based on the manuscript, by now translated into Russian, my father in 1935-1936 gave a lecture course at the Karpov Institute, attended also by young researchers from other institutes in Moscow. Since my father’s Russian was not perfect, his PhD students sometimes had to help him find appropriate terms for notions that were new also in German. The eager Russian listeners offered their criticism and proposed corrections, for which my father expressed gratitude in the preface of “Quantum Chemistry” (Квантовая Химия, Volume 1 in the series “Physics in Monographs” ONTI, Moscow and Leningrad, 546 pages), which appeared in early 1937. More specifically, it includes an acknowledgment to his friend and colleague Yuri Rumer.

Even before completing the Russian version, my father had started revising and tightening the German version. It carried the title “Einführung in die Quantenchemie” (Deuticke, Leipzig and Vienna, 350 pages) and appeared in late 1937. While the Russian version was written for a largely unprepared reader, the shorter German version, with about the same content, placed significantly higher requirements on the reader’s preparation. But while the Russian book was selling well and was soon out of print, the German book had far fewer buyers. The reasons are possibly the contemporary historical circumstances on the one hand and the events which occurred after the publication of the books on the other hand.

*     *

In 1937, mass arrests of the “enemies of the people” began in the Soviet Union. Among those arrested were German and Russians, writers and farmers, engineers and artists, officers and soldiers. No one could sleep peacefully any more. The total number of innocent victims in those years amounts to over twenty million. In a letter to his mother from December 1937, my father wrote that “the current international situation has become complicated” and that he did not want to write her more often. In the night from the 9th to the 10th of March 1938, my father was arrested. I was eight and a half years old and I can still remember this event. They woke me up and searched my bed for anti-Soviet writings and evidence of espionage activities.

My father’s doctoral student M. Kovner, who often visited our house, came to Moscow from Voronezh a few days later. He wanted to visit us, but a neighbor warned him against it and told him about my father’s arrest. As the result he had to leave immediately. Later, M. Kovner published two articles about his dear teacher.

After my father’s arrest, my mother tried several times to get information on his fate from the People’s Commissariat for Internal Affairs (NKVD), the predecessor of the KGB, all in vain. She was forced, by the threats from local officials, to end her inquiries. We had to leave Moscow. My mother found a job as a German language teacher at a middle school in a village 120 km west of Moscow (near Volokolamsk). We knew nothing about my father’s fate. Former friends disappeared likewise or avoided us. Only a few people maintained friendly contact with us: the Livshits family (my mother’s relatives) and the translator Nadezhda Volpina.

Several months after the start of the Russian campaign of the German Wehrmacht, on September 9, 1941, when German troops were already on the march to Moscow, my mother was arrested. We found each other again until after the war. She was accused of “anti-Soviet propaganda,” and it was claimed that she, a Jew who had fled Nazi Germany, had been waiting for the German troops to work for them as a translator. After several months in Moscow prison, she was exiled to the Semipalatinsk area in Kazakhstan.

Only after Stalin’s death, and the beginning of the politics of “the Thaw,” my mother was “fully rehabilitated.” She then requested information about her husband. Initially she received a certificate, which later turned out to be wrong, that he died in prison from a disease (peritonitis). Then my mother applied for a certificate of rehabilitation for my father, which she received in 1957. Now my father was “fully rehabilitated.” Sadly, this happened only after his death. Only in 1989, during the “perestroika,” did we get the real death certificate. The documents showed that my father was convicted to “high treason” and “espionage in favor of Germany” in accordance with Article 58 of the Criminal Code and was shot dead on May 29, 1938.

Already in May 1937, shortly after the beginning of mass arrests, Albert Einstein sent a letter to Stalin expressing his great concern for the fate of many well-known scientists. A similar letter from three Nobel laureates Irène Joliot-Curie, Frédéric Joliot-Curie, and Jean Baptiste Perrin was sent to Stalin in June 1937. But their voices were not heard. When Wilhelm Jost noticed in 1938 that the name “Hellmann” no longer appeared among the authors in the journal Acta Physicochimica URSS where my father worked and regularly published until October 1937, he asked his British colleague John Lennard-Jones for help. Lennard-Jones sent a request for reprints to my father’s address at the Karpov Institute, but there was no reply.

Due to the historical and political circumstances and the tragic fate caused by them, for decades my father’s name disappeared almost completely from science. Although his book “Einführung in die Quantenchemie” appeared in the US in 1944 as a war booty, it hardly found the wide dissemination which it deserves. The name “Hellmann” is now remembered mostly through the term “the Hellmann-Feynman theorem”…